Addition of heteroatom nucleophiles to ketene dimers
نویسندگان
چکیده
منابع مشابه
Addition of silylated nucleophiles to α-oxoketenes.
A general evaluation of silylated nucleophiles to intercept transient α-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid, efficient and easy-to-handle way. Mechanistic studies by DFT calculations and some post-functionalizations are discussed.
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ژورنال
عنوان ژورنال: Arkivoc
سال: 2021
ISSN: 1551-7012
DOI: 10.24820/ark.5550190.p011.441